An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte or a vacuum). The word was coined by the scientist Michael Faraday from the Greek words elektron (meaning amber, from which the word electricity is derived) and hodos, a way.
Polarizable and Non-Polarizable Electrodes :
Perfectly Polarizable Electrodes :
These are electrodes in which no actual charge crosses the electrode-electrolyte interface when a current is applied. The current across the interface is a displacement current and the electrode behaves like a capacitor. Example : Ag/AgCl Electrode
Perfectly Non-Polarizable Electrode
These are electrodes where current passes freely across the electrode-electrolyte interface, requiring no energy to make the transition. These electrodes see no overpotentials. Example : Platinum electrode
Commonly Used Biopotential Electrodes :
Metal plate electrodes :
–Large surface: Ancient, therefore still used, ECG
–Metal disk with stainless steel; platinum or gold coated
–EMG, EEG
–smaller diameters
–motion artifacts
–Disposable foam-pad: Cheap
Suction Cup electrodes
- No straps or adhesives required
- precordial (chest) ECG
- can only be used for short periods
Floating electrodes
- metal disk is recessed
- swimming in the electrolyte gel
- not in contact with the skin
- reduces motion artifact
Needle and wire electrodes for percutaneous measurement of biopotentials
Fetal ECG Electrodes :
Electrodes for detecting fetal electrocardiogram during labor, by means of intracutaneous needles (a) Suction electrode. (b) Cross-sectional view of suction electrode in place, showing penetration of probe through epidermis. (c) Helical electrode, which is attached to fetal skin by corkscrew type action.
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